Authors:
K. Lázár Institute of Isotopes P.O.B. 77 H-1525 Budapest Hungary

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A. M.-Szeleczky Institute of Isotopes P.O.B. 77 H-1525 Budapest Hungary

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G. Vorbeck Centre for Heterogeneous Catalysis Rudower Chaussee 5 D-1199 Berlin, Adlershof Germany

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R. Fricke Centre for Heterogeneous Catalysis Rudower Chaussee 5 D-1199 Berlin, Adlershof Germany

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A. Vondrova J. Heyrovsky Institute of Physical Chemistry Dolejskova 3 18223 Prague 8 Czech Republic

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J. Cejka J. Heyrovsky Institute of Physical Chemistry Dolejskova 3 18223 Prague 8 Czech Republic

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Abstract  

Ferrisilicates of MFI structure (HZSM-5) with Si/Fe ratios of 27.5, 35 and 67 have been studied by in situ Mössbauer spectroscopy, and the results are correlated with studies on catalytic conversions of toluene. Various species of iron ions are identified from 300 K spectra recorded after combinations of evacuation and reduction at 570 and 670 K, respectively. The roles of identified species are suggested in catalytic processes.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)