Authors:
Y. Yamada The University of Tokyo Department of Chemistry, School of Science 7-3-1 Hongo 113 Bunkyo-ku, Tokyo Japan

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K. Onaka The University of Tokyo Department of Chemistry, School of Science 7-3-1 Hongo 113 Bunkyo-ku, Tokyo Japan

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C. Obayashi The University of Tokyo Department of Chemistry, School of Science 7-3-1 Hongo 113 Bunkyo-ku, Tokyo Japan

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H. Sato Science University of Tokyo Department of Chemistry, Faculty of Science 1-3 Kagurazaka, Shinjyuku-ku 162 Tokyo Japan

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T. Tominaga The University of Tokyo Department of Chemistry, School of Science 7-3-1 Hongo 113 Bunkyo-ku, Tokyo Japan

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Abstract  

Mössbauer parameters of tin compounds, Sn(CH3)nCl4–n (n=0, 1, 2, 3, 4), isolated in low temperature matrices are correlated with electronic properties at the tin nuclei obtained by molecular orbital calculations. The Mössbauer isomer shift and quadrupole splitting show good correlation with electron density and electric field gradient estimated by molecular orbital calculations, respectively. Structures of novel species (Sn(CH3)2CH2 and [Sn(CH3)2CH2]2) produced via photodissociation of Sn(CH3)4 in low temperature matrices were estimated by means of molecular orbital calculations as compared with Mössbauer parameters.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)