Role of the water of crystallization in the Mössbauer spectra of some low-spin ferric and high-spin ferrous compounds. Its implications in comparative studies

E. Reguera; J. Fernández-Bertrán

doi:10.1007/bf02162885

Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 200: Issue 5

Role of the water of crystallization in the Mössbauer spectra of some low-spin ferric and high-spin ferrous compounds. Its implications in comparative studies

Authors:

E. Reguera

E. Reguera National Center for Scientific Research Division of Chemistry Ave. 25 and 158 Str., Cubanacan P. O. Box 6990 Havana Cuba

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J. Fernández-Bertrán

J. Fernández-Bertrán National Center for Scientific Research Division of Chemistry Ave. 25 and 158 Str., Cubanacan P. O. Box 6990 Havana Cuba

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Pages:: 443–455

Online Publication Date:: 27 Sep 2005

Publication Date:: 17 Jul 1995

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02162885

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Abstract

Mössbauer spectra of low-spin ferric and high-spin ferrous compounds may be sensitive to the local humidity during the measuring process or to other parameters associated with the hydration degree of the sample. This effect is related to the location of water molecules around the t_2g orbitals (d_xy, d_xz, d_yz). The results indicate that for comparative studies all Mössbauer measurements must be carried out in well standardized conditions.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)