Caesium salts of titanium, zirconium and thorium cyanoferrates(II)

V. Kouřím; M. Lázníček; J. Doležal

doi:10.1007/bf02516319

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 21: Issue 2

Caesium salts of titanium, zirconium and thorium cyanoferrates(II)

Authors:

V. Kouřím

V. Kouřím Nuclear Research Institute 25068 Řež (Czechoslovakia)

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M. Lázníček

M. Lázníček Nuclear Research Institute 25068 Řež (Czechoslovakia)

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J. Doležal

J. Doležal Nuclear Research Institute 25068 Řež (Czechoslovakia)

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Pages:: 355–362

Online Publication Date:: 09 Jan 2007

Publication Date:: 01 Sep 1974

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02516319

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Abstract

The synthesis of cyanoferrates of quadrivalent metals and the sorption of caesium ions by these materials have been studied. It has been found that the compositions of the compounds and their properties are strongly influenced by the degree of hydrolysis of the metal. These is no sorption of caesium by Zr⁴⁺ and Th⁴⁺ cyanoferrates, while the compounds of oxygencontaining bivalent complex cations exhibit behaviour similar to that of the other bivalent metals. The sorption of caesium by (TiO)₂R is govermed by an ion-exchange mechanism; with (ZrO)₂R changes occur in the crystal lattice, and (ThO)₂R exhibits a low affinity towards caesium.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)