Phase behaviour near the triple point of carbon dioxide confined in mesoporous VYCOR glass

J. Duffy; H. Fretwell; A. Clarke; S. Dugdale; M. Alam

doi:10.1007/bf02036270

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 211: Issue 1

Phase behaviour near the triple point of carbon dioxide confined in mesoporous VYCOR glass

Authors:

J. Duffy

J. Duffy Universität der Bundeswehr München Institut für Nukleare Festkörperphysik D-85579 Neubiberg (Germany)

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H. Fretwell

H. Fretwell University of Bristol H. H. Wills Physics Laboratory Tyndall Av. BS8 1TL Bristol (UK)

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A. Clarke

A. Clarke University of Bristol H. H. Wills Physics Laboratory Tyndall Av. BS8 1TL Bristol (UK)

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S. Dugdale

S. Dugdale University of Bristol H. H. Wills Physics Laboratory Tyndall Av. BS8 1TL Bristol (UK)

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, and

M. Alam

M. Alam University of Bristol H. H. Wills Physics Laboratory Tyndall Av. BS8 1TL Bristol (UK)

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Pages:: 173–179

Online Publication Date:: 13 Aug 2005

Publication Date:: 17 Nov 1996

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02036270

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Abstract

The phase behaviour of carbon dioxide confined in VYCOR glass at pressures below that of the bulk triple point (0.51 MPa) has been investigated. The temperature at which freezing occurs appears to be pressure dependent below 0.3 MPa. As experiments are performed at successively lower pressures, the confined phase transitions gradually disappear, due to either partial pore filling, or the proximity of the confined triple point.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)