Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 220: Issue 2
Substoichiometric isotope dilution mass spectrometry as a new analytical method
Authors:
H. Imura Ibaraki University Department of Environmental Sciences, Faculty of Science 310 Mito Japan

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H. Sakamoto Ibaraki University Department of Environmental Sciences, Faculty of Science 310 Mito Japan

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K. Ohashi Ibaraki University Department of Environmental Sciences, Faculty of Science 310 Mito Japan

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T. Shirasaki Hitachi Instruments Engineering Co., Ltd. 312 Katsuta Japan

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K. Oishi Hitachi, Ltd. Instrument Div. 312 Katsuta Japan

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Pages:
191–193
Online Publication Date:
14 Aug 2005
Publication Date:
01 Jun 1997
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02034854
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Abstract  

A novel analytical method, the substoichiometric isotope dilution mass spectrometry (SIDMS) has been proposed. This method consists of the substoichiometric separation of the element in question and the subsequent intensity measurement of a stable isotope of the element with a mass spectrometer. In SIDMS, the correction of the mass discrimination of isotope measurement is not necessary and the use of expensive enriched stable isotopes may be avoided. The validity and the usefulness of SIDMS are demonstrated by the substoichiometric extraction of iron(III) with 4-isopropyltropolone and 3,5-dichlorophenol following microwave-induced plasma mass spectrometry.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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