Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 220: Issue 2
Carbon-13 intermolecular isotope effect in the decarbonylation of liquid extra pure Merck formic acid
Authors:
M. Zieliński Jagiellonian University Isotope Laboratory (Laboratory of Nuclear Chemistry), Faculty of Chemistry Kraków Poland

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A. Zielińska Jagiellonian University Isotope Laboratory (Laboratory of Nuclear Chemistry), Faculty of Chemistry Kraków Poland

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S. Bernasconi ETH (Swiss Federal Institute of Technology), Zürich Laboratory of Stable Isotopes (Geologisches Institut) CH-8092 Zürich Switzerland

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H. Papiernik-Zielińska Jagiellonian University Isotope Laboratory (Laboratory of Nuclear Chemistry), Faculty of Chemistry Kraków Poland

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Pages:
263–265
Online Publication Date:
14 Aug 2005
Publication Date:
01 Jun 1997
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02034870
Restricted access

Abstract  

Intemolecular13C isotope effects in the decarbonylation of extra pure Merck liquid formic acid have been determined in the temperature interval 50–100 °C and compared to13C KIE observed in the decomposition of 99.9% liquid formic acid in the temperature range 60–100 °C. A very constants in the Arrhenius and Eyring equations have been calculated and found to be in a good agreement with the corresponding values ofBarham andClark.8

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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