Authors:
X. Huang Tianjin University Department of Chemical Engineering 300072 Tianjin P.R. China

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R. Wang Tianjin University Department of Chemical Engineering 300072 Tianjin P.R. China

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Abstract  

Direct anchoring of the synergistic extractant TOPO-P204 onto the inner walls of mesoporous molecular sieve generates a non-stoichiometric synergistic extractive membrane absorbent: MCM-TP which has well-spaced and structurally well defined active sites. Specifically, the feasibility of applying the MCM-TP absorbent with an absorption capacity of 0.02 mmol[Pd]/gabsorbent to the recovery of non-radioactive palladium from spent nuclear fuels has been examined showing an advantage over the liquid-liquid extraction or precipitation method. MCM-TP studied by powder XRD, TEM and29Si MAS NMR indicates that it has 35 Å regular, well-defined channels and an improved hydrothemal stability.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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