Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 23: Issue 1-2
Heterogeneous exchange reactions of unstable simple systems
Authors:
A. Azzam Ain Shams University Chemistry Department, Faculty of Science Cairo (A.R. Egypt)

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A. El-Atrash Ain Shams University Chemistry Department, Faculty of Science Cairo (A.R. Egypt)

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, and
N. Ghattas Ain Shams University Chemistry Department, Faculty of Science Cairo (A.R. Egypt)

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Pages:
63–71
Online Publication Date:
12 Oct 2006
Publication Date:
01 Mar 1974
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02514345
Restricted access

Abstract  

Carrier-free strontium and cesium isotopes were used to study the heterogeneous exchange of the systems strontium/strontium carbonate and cesium/cesium tetraphenylborate. The elements under consideration are among the long-lived isotopes most desired to be removed from waste solutions and consequently the use of heterogeneous exchange as an applied phenomenon for selective fixation is possible. The results obtained show that the above two systems are unstable ones (i. e., undergoing either formation or dissolution of the precipitated solid phase). New modified equations were proposed for quantitative calculation of the fraction of exchange, using only radiometric data and avoiding the use of microanalytical data. The equations are useful for all unstable systems, especially if no precise microquentitative method of analysis is known for the element under consideration. Recrystallization and self-diffusion were proposed to explain the two parts characterizing the exchange curves.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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