Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 232: Issue 1-2
Coordination sphere symmetry of di-n-butyltin(IV) complexes containing ligands with {O,O} donor atoms
Authors: K. Gajda-Schrantz 1 , L. Nagy 1 , E. Kuzmann 2 , and A. Vértes 2
View More View Less
  • 1 A. József University Department of Inorganic and Analytical Chemistry P.O. Box 440 H-6701 Szeged Hungary
  • 2 L. Eötvös University Department of Nuclear Chemistry Budapest Hungary
DOI:
https://doi.org/10.1007/bf02383732
Page Count:
151–158
Publication Date:
17 Jun 1998
Online Publication Date:
12 Apr 2006
Article Category:
Research Article
Restricted access

Abstract  

Eight di-n-butyltin(IV) complexes with glycolic, 2-hydroxy-propionic, succinic and malic acids, have been prepared by two different procedures. The compounds were characterised by elemental analysis, FTIR, Raman and119Sn Mössbauer spectroscopy. The IR and Raman data indicated the presence of bidentate and/or monodentate carboxylate groups, non linear C−Sn−C bonds, and Sn−O bonds within the complexes. The results of Mössbauer spectroscopic measurements, based on point-charge model calculations, have shown the occurrence of trigonal bipyramidal environment in the central tin(IV) atom, besides the octahedral and tetrahedral structure.

Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Sep 2020 0 0 0
Oct 2020 0 0 0
Nov 2020 0 7 3
Dec 2020 0 0 0
Jan 2021 0 0 0
Feb 2021 1 0 0
Mar 2021 0 0 0