Mössbauer spectra of (Fe0.5Zn0.5)PS3 and its pyridine intercalate

H. Sakai; T. Yamazaki; N. Machida; T. Shigematsu; S. Nakashima

doi:10.1007/bf02349490

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 239: Issue 2

Mössbauer spectra of (Fe_0.5Zn_0.5)PS₃ and its pyridine intercalate

Authors:

H. Sakai

H. Sakai Konan University, Higashi-nada Department of Chemistry, Faculty of Science 658 Kobe Japan

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T. Yamazaki

T. Yamazaki Konan University, Higashi-nada Department of Chemistry, Faculty of Science 658 Kobe Japan

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N. Machida

N. Machida Konan University, Higashi-nada Department of Chemistry, Faculty of Science 658 Kobe Japan

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T. Shigematsu

T. Shigematsu Konan University, Higashi-nada Department of Chemistry, Faculty of Science 658 Kobe Japan

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S. Nakashima

S. Nakashima Hiroshima University Radioisotope Center Kagamiyama 739 Higashi-Hiroshima Japan

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Pages:: 241–244

Online Publication Date:: 10 Apr 2006

Publication Date:: 17 Feb 1999

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02349490

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Abstract

Mössbauer spectra of (Fe_0.5Zn_0.5)PS₃, which is isomorphous with FePS₃, were measured at 300 and 80 K, and were compared with those of FePS₃. We succeeded in preparing (Fe_0.5Zn_0.5)PS₃ intercalated with pyridine. In the XRD pattern of the intercalate the diffraction peaks corresponding to (Fe_0.5Zn_0.5)PS₃ were completely missing, suggesting that the intercalation was completely performed with pyridine. The Mössbauer spectra were changed significantly by the intercalation suggesting the charge transfer from guest molecules to the host matrix. The replacement of iron by zinc has no influence on the electronic state of the iron atom, except for the magnetic interaction.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)