Authors:
T. Kaneko Niigata University Department of Chemistry, Faculty of Science 950-2181 Niigata Japan

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K. Tamura Niigata University Department of Chemistry, Faculty of Science 950-2181 Niigata Japan

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S. Kimura Niigata University Department of Chemistry, Faculty of Science 950-2181 Niigata Japan

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H. Kudo Niigata University Department of Chemistry, Faculty of Science 950-2181 Niigata Japan

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Abstract  

The complex formation of LaCl3 with dipivaloylmethane (dpm) was investigated in a view of the applicability to a rapid chemistry. It was found that the complex formation of lanthanum chloride with dpm in a gas phase was recognized and a volatile LaCl2 (dpm) which was formed by substitution of a chloride atom in LaCl3 by dpm molecule was mainly produced. A temperature dependence of LaCl2 (dpm) formation was examined and the activation energy of the reaction was deduced.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)