Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 240: Issue 2
Contribution to the thermodynamics of complexes of alkali metal cations with 18-crown-6 in the water—nitrobenzene extraction system
Authors:
E. Makrlík Charles University Faculty of Education 11639 Prague 1 Czech Republic

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P. Vaňura Prague Institute of Chemical Technology Department of Analytical Chemistry 166 28 Prague 6 Czech Republic

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M. Daňková Kremlickova 964 280 00 Kolín II Czech Republic

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Pages:
579–583
Online Publication Date:
10 Apr 2006
Publication Date:
17 May 1999
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02349416
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Abstract  

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+(aq)+NaL+(nb)⇄ML+(nb)+Na+(aq) taking place in the two-phase water-nitrobenzene system (M+=Li+, K+, Rb+, Cs+; L=18-crown-6; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. The stability constants of the ML+ complexes in nitrobenzene saturated with water were calculated; they are found to increase in the cation order Cs+Li+Na+Rb+K+. Further, the individual extraction constants for the NaL+, KL+, RbL+ and CsL+ complex species in the wate-nitrobenzene system were determined; their values increase in the series Na+Rb+Cs+K+.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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