Authors:
T. Nishida Kyushu University, Hakozaki Department of Chemistry, Faculty of Science Higashiku Fukuoka 812-8581 Japan

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K. Maki Kyushu University, Hakozaki Department of Chemistry, Faculty of Science Higashiku Fukuoka 812-8581 Japan

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Abstract  

57Fe Mössbauer spectra of 30CaO·15Al2O3·5Fe2O3·25PbO·25P2O5 glass consist of two quadrupole doublets due to distorted Fe(III)O6 and Fe(II)O6 octahedra. Mössbauer spectra of the aluminophosphate glass irradiated with60Co γ-rays (≈5·104Gy) were essentially the same as those of non-irradiated glass. Mössbauer spectra of γ-ray irradiated aluminophosphate glass, containing 10 stable isotopes (Sr, Y, Zr, Nb, Mo, Ba, La, Ce, Pr, and Nd) as the simulated nuclear waste, were also the same as those of non-irradiated glass. These results indicate that the aluminophosphate glass containing iron and lead has high radiation-durability, in addition to high heat resistivity and high water resistivity.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)