Authors:
M. Yeh Washington State University Chemistry Department and Nuclear Radiation Center Pullman WA 99164-4630 USA

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A. Maddison Washington State University Chemistry Department and Nuclear Radiation Center Pullman WA 99164-4630 USA

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S. Clark Washington State University Chemistry Department and Nuclear Radiation Center Pullman WA 99164-4630 USA

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Abstract  

The influence of elevated temperatures on the formation of 1:1 chloro complexes for Eu3+ and Am3+ are reported. Using a solvent extraction technique, stability constants for the equilibrium M(aq)3++Cl(aq)MCl(aq)2+ have been measured in the temperature range of 25–75 °C. Modest increases in 1 are observed, and small positive enthalpies for these reactions are reported. These data are discussed in the context of previous reports for the trivalent lanthanide and actinide chloro systems.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)