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  • 1 KFKI Research Institute for Particle and Nuclear Physics H-1525 Budapest P.O. Box 49 Hungary
  • | 2 Research Institute for Solid State Physics and Optics H-1525 Budapest P.O. Box 49 Hungary
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Abstract  

Soon after the discovery of the Mössbauer effect, studies were performed on spinels containing various transition metal ions (mostly Fe2+). This method proved very useful for investigating the local symmetry at transition metal ions. In spite of the numerous results, the correct interpretation of the complex quadrupole split spectra is still not given for numerous spinel structures. Since spectra of different shapes were measured for FeAl2O4 and FeCr2O4 by different authors, we performed new measurements on these spinels. The results on FeAl2O4 showed that the statistical distribution of another kind of ions in the positions A may influence the electric field gradient at the Fe2+ ions in the tetrahedral interstices. In FeCr2O4 and in the mixed Fe0.5Mg0.5Cr2O4, the electric field gradient exists at the Fe2+ ions at room temperature indicating that the degeneracy of the orbital doublet of the Fe2+ is removed.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)