Authors:
Gy. Vankó Hungarian Academy of Sciences at Eötvös L. University Budapest Research Group for Nuclear Techniques in Structural Chemistry H-1518 Budapest P.O. Box 32 Hungary

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L. Bottyán KFKI Research Institute for Particle and Nuclear Physics H-1525 Budapest P.O. Box 49 Hungary

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D. Nagy KFKI Research Institute for Particle and Nuclear Physics H-1525 Budapest P.O. Box 49 Hungary

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E. Szilágyi KFKI Research Institute for Particle and Nuclear Physics H-1525 Budapest P.O. Box 49 Hungary

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A. Vértes Hungarian Academy of Sciences at Eötvös L. University Budapest Research Group for Nuclear Techniques in Structural Chemistry H-1518 Budapest P.O. Box 32 Hungary

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Abstract  

Nuclear inelastic resonant scattering of synchrotron radiation was applied to the study solutions of 57Fe complexes. In order to reveal different inelastic contributions solutions of two different 57Fe complexes of different molecular dimensions with solvents of substantially different viscosities were studied. We argue that the only former experiment available in the literature overestimates the role of the diffusivity in affecting the spectrum. The first direct observation of an intramolecular vibrational transition assisting the nuclear resonance absorption in a liquid is reported.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)