The irradiation of atmospheric air with high-energy protons has been performed at the 12 GeV proton synchrotron. The specific activity of 13N, one of the principal airborne radioactivities, was measured as a function of the irradiation time at a dose rate of about 6·1016 eV/g/s, and compared with the calculated values. The predominant chemical species of 13N produced were found to be 13N2and 13NO2. Their proportions were approximately 55% for 13N2 and 45% for13NO2, being almost independent of the irradiation time. Smaller quantities of 13NO and H13NO2 were also observed. Measurements of radiolytic products showed that ozone is a main product and that NO2predominates among the products of nitrogen compounds, including HNO2 and HNO3. The G-value for ozone formation in air was estimated from the experimental data as 6.4 molecules/100 eV.