Rapid determination of 99Tc in environmental samples by high resolution ICP-MS coupled with on-line flow injection system

C. Kim; B. Rho; J. Lee

doi:10.1023/a:1015799229683

Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 252: Issue 2

Rapid determination of ⁹⁹Tc in environmental samples by high resolution ICP-MS coupled with on-line flow injection system

Authors:

C. Kim

C. Kim Korea Institute of Nuclear Safety Department of Radiation and Engineering Research Yusong, Taejon 305-338 Korea

Search for other papers by C. Kim in
Current site
Google Scholar
PubMed

B. Rho

B. Rho Korea Institute of Nuclear Safety Department of Radiation and Engineering Research Yusong, Taejon 305-338 Korea

Search for other papers by B. Rho in
Current site
Google Scholar
PubMed

, and

J. Lee

J. Lee Korea Institute of Nuclear Safety Department of Radiation and Engineering Research Yusong, Taejon 305-338 Korea

Search for other papers by J. Lee in
Current site
Google Scholar
PubMed

View More View Less

Pages:: 421–427

Online Publication Date:: 01 Nov 2004

Publication Date:: 17 May 2002

Article Category:: Research Article

DOI:: https://doi.org/10.1023/a:1015799229683

Restricted access

Abstract

High resolution inductively coupled plasma mass spectrometry coupled with an on-line flow injection system (FI-HR-ICP-MS) was applied to determine the ultra-trace level ⁹⁹Tc in soil. The flow injection system (PrepLab) was composed of two TEVA-Spec^Òresins, reduced remarkably the sample amounts and the analysis time, compared to the conventional analytical methods. In the flow injection system, Mo and Ru were sufficiently eliminated by using the flow injection system, with the decontamination factors of 1.6^.10⁴ and 9.9^.10⁵, respectively. With the present method, it was possible to determine ultra-low level of ⁹⁹Tc in 3-6 g soil at 3–5 hours of analysis time per sample. The relative standard deviation for each sample was less than 4%. The detection limits for ⁹⁹Tc was 85 fg^.ml^–1 (0.05 mBq^.ml^–1), which was calculated from the three times standard deviation of the count rate of the blank.

Save
Cite
Email this content

Share Link

Copy this link, or click below to email it to a friend
Email this content
or copy the link directly:

https://akjournals.com/abstract/journals/10967/252/2/article-p421.xml
The link was not copied. Your current browser may not support copying via this button.

Link copied successfully

Collapse
Expand

Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)