Pyrite FeS2 was laser-deposited onto Al substrates at various temperatures, and the Mössbauer spectra of the films were measured. The yields and the Mössbauer parameters of FeS2 and FeS changed depending on the formation temperature, because of the sulfur deficiency in the lattice structures. In addition, hematite Fe2O3 was employed as a laser-ablation target, and FeO and Fe2O3 were deposited on SiO2/Si substrates. It was shown that laser-deposition of compounds can produce films that have different chemical species than the laser-evaporated materials.