Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 277: Issue 2
New extraction chromatographic material for rhenium separation
Authors:
M. Lučaníková

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,
J. Kučera

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, and
F. Šebesta Czech Technical University in Prague Centre for Radiochemistry and Radiation Chemistry Břehová 7 115 19 Prague 1 Czech Republic

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Pages:
479–485
Online Publication Date:
12 Mar 2008
Publication Date:
01 Aug 2008
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10967-007-7153-8
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Abstract  

AbstractThree types of the extraction chromatographic materials, composed from Aliquat® 336 deposited in the polyacrylonitrile (PAN) beads and prepared by different procedures, were compared for extraction of rhenium. The best properties were exhibited when the solid extractant was prepared by impregnation of the ready-made PAN beads. Solid extractant prepared by direct coagulation of the beads from the suspension of Aliquat® 336 in solution of PAN in nitric acid differs only by lower capacity in dynamic conditions. Material prepared from the PAN solution in dimethylsulfoxide was the worst because Aliquat® 336 was washed out from the beads during coagulation of the polymer and the extraction capacity was low. As it is shown, the first two solid extractants are fully comparable with the commercial TEVA Resin.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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