Authors:
M. Răileanu “Al. I. Cuza” University of Iaşi Faculty of Chemistry Department of Inorganic and Analytical Chemistry 11 - Carol I, Blvd. 700506 Iaşi Romania

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A. Cecal “Al. I. Cuza” University of Iaşi Faculty of Chemistry Department of Inorganic and Analytical Chemistry 11 - Carol I, Blvd. 700506 Iaşi Romania

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Abstract  

The present paper deals with the retention of U(IV) and U(VI) species, both individually and in 1 :1 mixtures, on some ion-exchange resins of the normal DGA (N,N’,N’-tetra-n-octyldiglycolamide), TEVA- [trialkyl methyl-ammonium nitrate (or chloride)] and UTEVA-type (dipentyl pentylphosphonate), in different experimental conditions. The degree of retention, distribution constant, as well as enthalpy and entropy values which characterize the adsorption of uranium ions on these resins were calculated. By means of Langmuir relation, taking into account the experimental data, the maximum adsorption capacity, Langmuir constant and Gibbs free energy values for the studied processes are established.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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