Authors:
E. Makrlík University of West Bohemia Faculty of Applied Sciences Husova 11 306 14 Pilsen Czech Republic

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P. Vaňura Institute of Chemical Technology Technická 5 166 28 Prague Czech Republic

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P. Selucký Nuclear Research Institute 250 68 Řež Czech Republic

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Abstract  

Extraction of microamounts of cesium by nitrobenzene solutions of sodium, ammonium and thallium dicarbollylcobaltates (M+B; M+ = Na+, NH4+, Tl+) in the presence of benzo-15-crown-5 (B15C5, L) has been investigated. The equilibrium data have been explained assuming that the complexes ML+ and ML2+ (M+ = Na+, NH4+, Tl+; L = B15C5) are present in the organic phase. The stability constants of the complex species ML+ and ML2+ in nitrobenzene saturated with water have been determined.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)