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  • 1 Department of Chemistry, Trace Analysis Research Centre, Dalhousie University, Halifax, NS B3H 4J3, Canada
  • | 2 Instituto Superior de Tecnologías y Ciencias Aplicadas, 6163, Havana, Cuba
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A method for the preconcentration of Cu(II) by cloud point extraction (CPE) followed by its determination using neutron activation analysis (NAA) was developed. The method involves the use of a nonionic surfactant, namely PONPE-7.5, and a chelating agent 1-(2-pyridylazo)-2-naphthol (PAN). The phase diagram of the surfactant was constructed and the effects of different additives on the cloud point were investigated. Factors, such as the solution pH, ionic strength, temperature, and concentrations of chelating agent and surfactant, which can influence the extraction efficiency of the metal, were optimized. The copper(II) chelate was extracted into a surfactant-rich phase of small volume with a recovery of nearly 100% and a preconcentration factor of 60. The small volume of the surfactant-rich phase obtained complies with the green chemistry concept, allowing the design of extraction procedures having lower toxicity than those using organic solvents. The method was applied to tap water samples.

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  • Impact Factor (2019): 1.137
  • Scimago Journal Rank (2019): 0.360
  • SJR Hirsch-Index (2019): 65
  • SJR Quartile Score (2019): Q3 Analytical Chemistry
  • SJR Quartile Score (2019): Q3 Health, Toxicology and Mutagenesis
  • SJR Quartile Score (2019): Q2 Nuclear Energy and Engineering
  • SJR Quartile Score (2019): Q3 Pollution
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  • SJR Quartile Score (2019): Q3 Radiology, Nuclear Medicine and Imaging
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  • Impact Factor (2018): 1.186
  • Scimago Journal Rank (2018): 0.408
  • SJR Hirsch-Index (2018): 60
  • SJR Quartile Score (2018): Q2 Nuclear Energy and Engineering
  • SJR Quartile Score (2018): Q2 Pollution

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
per Year
per Year
Founder Akadémiai Kiadó
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)