Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 30: Issue 1
Different alternatives for stability constant determination of Zr and Hf 2-methyl lactate complexes by cation exchange
Authors:
H. Aly Atomic Energy Establishment Cairo (Egypt)

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,
M. El-Haggan Atomic Energy Establishment Cairo (Egypt)

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, and
A. Abdel-Rassoul Atomic Energy Establishment Cairo (Egypt)

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Pages:
81–92
Online Publication Date:
09 Jan 2007
Publication Date:
01 Mar 1976
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02516620
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Abstract  

Three different alternatives are applied for the determination of the stability constants of zirconium and hafnium complexes with 2-methyl lactic acid using cation exchange. Calculations based on the exchange equilibria of the highly charged metal cations and the positively charged ligand complexes rather than that of the hydrolysed complex species are worked out according to SCHUBERT and FRONAEUS, respectively. The third alternative adopted in this work, is principally based on the consideration of all complexed species produced by hydrolyses in the aqueous phase. The B-values obtained by the different methods are intercorrelated and discussed.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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