Authors:
M. Cheema Pakistan Institute of Nuclear Science and Technology Nuclear Chemistry Division P. O. Nilore Rawalpindi (Pakistan)

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I. Qureshi Pakistan Institute of Nuclear Science and Technology Nuclear Chemistry Division P. O. Nilore Rawalpindi (Pakistan)

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M. Ashraf Pakistan Institute of Nuclear Science and Technology Nuclear Chemistry Division P. O. Nilore Rawalpindi (Pakistan)

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Imtiaz Hanif Pakistan Institute of Nuclear Science and Technology Nuclear Chemistry Division P. O. Nilore Rawalpindi (Pakistan)

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Abstract  

Extraction behaviour of the chelates of group VB–VIIB and VIII elements using 1-(2-pyridylazo)-2-naphthol (PAN) has been studied as a function of pH. Studies have been made to back-extract the metal ions from the organic phase into the aqueous solution containing the optimum concentration of KCN and HClO4 and buffers of appropriate pH. The masking agents such as citrate, cyanide, thiosulphate, fluoride and thiourea were used to achieve more specific separations. The studies indicate the potentiality of PAN as a useful solvent extracting reagent in devising group chemical separation procedures for activation analysis.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)