Journal of Radioanalytical and Nuclear Chemistry
Volume/Issue:
Volume 36: Issue 2
Studies on the ion-exchange behaviour of chromium ferrocyanide
Authors:
W. Malik University of Roorkee Department of Chemistry Roorkee U.P. India

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S. Srivastava University of Roorkee Department of Chemistry Roorkee U.P. India

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Raj Singh University of Roorkee Department of Chemistry Roorkee U.P. India

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Satish Kumar University of Roorkee Department of Chemistry Roorkee U.P. India

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Pages:
469–477
Online Publication Date:
09 Jan 2007
Publication Date:
01 Sep 1977
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02517015
Restricted access

Abstract  

The sorption of univalent, bivalent and trivalent ions has been studied on chromium ferrocyanide gel. The studies reveal a high sorption capacity for Cs+, Tl+, Ag+, Cu2+, Zn2+, Cd2+, Fe3+ and Th4+. The sorption of monovalent cations show purely ion-exchange mechanism while the uptake of bivalent and trivalent cations is non-equivalent in nature. Single elution of Rb+, Cs+ and Tl+ has been performed from the columns of this exchanger and the recovery is almost complete in all the cases. Cu2+ and Ag+ get completely adsorbed on the gel column and their elution is not possible probably due to the formation of some new solid phases. Depending on the Kd values of the metal ions, a large number of separations of radiochemical as well as analytical importance can be performed on the columns of this exchanger material.

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Cover Journal of Radioanalytical and Nuclear Chemistry
Journal of Radioanalytical and Nuclear Chemistry
Print ISSN:
0236-5731
Online ISSN:
1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation		 1968
Volumes
per Year		 1
Issues
per Year		 12
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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