Authors:
H. Aly Atomic Energy Establishment Nuclear Chemistry Department Cairo Egypt

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M. Abdel-Hamid Atomic Energy Establishment Nuclear Chemistry Department Cairo Egypt

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A. Abdel Rassoul Atomic Energy Establishment Nuclear Chemistry Department Cairo Egypt

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Abstract  

The distribution coefficient of sulphide, sulphite, sulphate and thiosulphate anions between different concentrations of aqueous alkali metal chloride solutions and the anion exchanger Dowex 1X8 is studied. The obtained distribution deportment of these anions is explained in the light of water-water, anion-cation and ion-ion interactions as well as the different tendencies of the alkali ions to hydration. Based on the separation factors encountered between adjacent anions, a chromatographic method is adopted for isolation of the sulphur anions by gradient elution. This method is further compared with the chromatographic procedures so far reported for separation of the investigated anions.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)