. The average cross-section of the103Rh(n, 2n)102Rh reaction in a fission neutron spectrum is about 0.75 mb. Irradiation of rhodium in the bremsstrahlung spectrum of 50 MeV
electrons yielded a102Rh activity of 0.11 μCi/g after 3 days at a power of 2 kW. The thick target yield of the reaction104Pd(d, α)102Rh was 0.002 μCi/μAh for 12 MeV deuterons. The thick target yield of the reaction Ru(d,xn)102Rh was 0.05 μCi/μAh for 12 MeV deuterons and 4.8 μCi/μAh for 18 MeV deuterons. The best yield was obtained by deuteron bombardment
of ruthenium. The chemical separation of carrier-free Rh radionuclides from deuteron-irradiated ruthenium is described, with
a chemical yield better than 90%. The same procedure has also been applied for the isolation of105Rh from neutron-irradiated ruthenium. γ-Ray spectra of99Rh,101(m)Rh and102(m)Rh from deuteron-irradiated ruthenium and of105Rh from neutron-irradiated ruthenium, taken with a Ge(Li) detector, are shown; a number of γ-rays, not reported in the literature,
were observed. The γ-ray energies were determined with a precision of ca. 0.3–0.4 keV.