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  • 1 Mendeleev Institute of Chemical Technology Moscow USSR
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The relation between the structure of olefins and oxygen-containing compounds and their reactivity in radical addition, substitution and isomerization processes under γ-irradiation in a wide temperature range was examined. Correlation equations for the determination of elementary rate constants and their Arrhenius parameters are given. The compensation effect is discussed. A mechanism of product formation is proposed and the corresponding kinetic equations are derived from the steady-state principle.