Authors:
W. Sanad Nuclear Chemistry Department Atomic Energy Establishment Cairo (Egypt)

Search for other papers by W. Sanad in
Current site
Google Scholar
PubMed
Close
,
H. Flex Nuclear Chemistry Department Atomic Energy Establishment Cairo (Egypt)

Search for other papers by H. Flex in
Current site
Google Scholar
PubMed
Close
, and
A. Haggag Nuclear Chemistry Department Atomic Energy Establishment Cairo (Egypt)

Search for other papers by A. Haggag in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract  

The equilibrium and rate of solvent extraction of FeCl3 complexes from HCl solutions into benzene solutions of tributyl phosphate (TBP) has been studied. The extracted species was found to be FeCl3·3TBP. The results show that the extraction is first order in both Fe(III) and TBP. The rate constant of adduct formation equals ∼1.24M min−1. The reaction order is zero for the aqueous phase acidity. The rate-controlling steps are discussed in the light of the results.

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)