Authors:
L. Kozári Institute of Isotopes of the Hungarian Academy of Sciences P.O.B. 77 H-1525 Budapest Hungary

Search for other papers by L. Kozári in
Current site
Google Scholar
PubMed
Close
,
L. Wojnárovits Institute of Isotopes of the Hungarian Academy of Sciences P.O.B. 77 H-1525 Budapest Hungary

Search for other papers by L. Wojnárovits in
Current site
Google Scholar
PubMed
Close
, and
G. Földiák Institute of Isotopes of the Hungarian Academy of Sciences P.O.B. 77 H-1525 Budapest Hungary

Search for other papers by G. Földiák in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract  

By comparing the composition of products formed during the -radiolysis of structural and geometrical /cis and trans/ isomers of dimethylcyclohexanes, the relationship between molecular structure and ring decomposition reactions was investigated. The yields of products that exist in geometrical isomeric forms /e.g. 2-butenes, 2-octenes/ were considerably different in the irradiation of cis- and transdimethylcyclohexanes: the products reflected the conformation of the decomposed molecule. It was assumed that the ring decomposition is a very fast process taking place within about 1 ps. If biradical intermediates are involved in the reactions, their further transformations occur before attaining conformational equilibrium.

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)