Author:
R. MahfouzAssiut University Faculty of Science, Chemistry Department Assiut Egypt

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Abstract  

The chemical effects of chromium neutron capture recoils produced in mixed crystals of the type K3Cr/C2O4/3–K3Al/C2O4/3 and K3Cr/CN/6–K3Al/CN/6 have been investigated. The initial parent retentions in the investigated mixed crystals have been determined using solvent extraction techniques and making use of 0.32 MeV photopeak for51Cr produced as a result of thermal neutron capture. It was found that initial chromium parent retentions varies linearly with parent mole fraction in the mixed crystals. The retention and non-retention results have been discussed in terms of a mechanistic model involving metal and ligand vacancies exchange and substitution reactions.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)

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