Radiolysis of 2-propanol in the presence of 1-(2-furanyl)-1-hexanone; The yields of hydrogen and methane

N. El-Assy; M. El-Dessouky; I. Gar Al-Alm Rashed

doi:10.1007/bf02040594

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 89: Issue 2

Radiolysis of 2-propanol in the presence of 1-(2-furanyl)-1-hexanone; The yields of hydrogen and methane

Authors:

N. El-Assy

N. El-Assy National Center for Radiation Research and Technology P.O. Box 29 Nasr City, Cairo (Egypt)

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M. El-Dessouky

M. El-Dessouky National Center for Radiation Research and Technology P.O. Box 29 Nasr City, Cairo (Egypt)

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I. Gar Al-Alm Rashed

I. Gar Al-Alm Rashed National Center for Radiation Research and Technology P.O. Box 29 Nasr City, Cairo (Egypt)

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Pages:: 305–314

Online Publication Date:: 14 Aug 2005

Publication Date:: 17 Apr 1985

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02040594

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Abstract

Hydrogen and methane produced during the -radiolysis of 2-propanol have been measured in the absence and presence of 0.1 and 0.01 M ketone (1-(2-furanyl)-1-hexanone) at different doses. In the absence of ketone at 100 kGy, the hydrogen and methane yields were found to be G(H₂)=5.1 and G(CH₄)=2.02. At lower ketone concentrations the hydrogen and methane yields were G(H₂)=4.35 and G(CH₄)=1.83, while higher concentrations decreased the above values to G(H₂)=2.95 and G(CH₄)=1.33, respectively. The radiolytic mechanism is discussed in detail.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)