Mössbauer study of interphase formation at the interface of electrodeposited tin on silver and platinum

H. Mehner; A. Vértes

doi:10.1007/bf02163035

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Journal of Radioanalytical and Nuclear Chemistry

Volume/Issue:: Volume 96: Issue 4

Mössbauer study of interphase formation at the interface of electrodeposited tin on silver and platinum

Authors:

H. Mehner

H. Mehner Academy of Sciences of the GDR Central Institute of Physical Chemistry DDR-1199 Berlin-Adlershof GDR

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and

A. Vértes

A. Vértes L. Eötvös University Laboratory of Nuclear Chemistry H-1088 Budapest Hungary

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Pages:: 353–361

Online Publication Date:: 27 Sep 2005

Publication Date:: 17 Nov 1985

Article Category:: Research Article

DOI:: https://doi.org/10.1007/bf02163035

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Abstract

During electrodeposition of Sn on Ag substrate an interphase formation /electroimplantation/ could be observed. The average thickness of the formed alloy amounts to 35 nm. Heat treatment increases the thickness of the interphase, the activation energy of the interdiffusion process is 45.5±2 kJ mol^–1. The system Sn on Pt substrate showed no electroimplantation. The diffusion during heat treatment has an activation energy of 126.2±2 kJ mol^–1. Isomer shift of the formed alloys indicates that Pt diffuses preferentially into the tin layer.

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Journal of Radioanalytical and Nuclear Chemistry

Print ISSN:: 0236-5731

Online ISSN:: 1588-2780

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Journal of Radionalytical and Nuclear Chemistry
Language	English
Size	A4
Year of Foundation	1968
Volumes per Year	1
Issues per Year	12
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	0236-5731 (Print)
ISSN	1588-2780 (Online)