Authors:
Y. Yamada The University of Tokyo Department of Chemistry, Faculty of Science Hongo Tokyo Japan

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Y. Minai The University of Tokyo Department of Chemistry, Faculty of Science Hongo Tokyo Japan

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H. Sato The University of Tokyo Department of Chemistry, Faculty of Science Hongo Tokyo Japan

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T. Tominaga The University of Tokyo Department of Chemistry, Faculty of Science Hongo Tokyo Japan

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Abstract  

The UV photolysis of pentacarbonyliron isolated in low temperature nitrogen matrix was studied by the Mössbauer Technique. Besides stable compounds /Fe2/CO/9 and Fe3/CO/12/ unstable species such as Fe/Co/4 and Fe2/CO/8 were produced by UV irradiation. Furthermore, the unstable species were found to react with nitrogen matrix, leading to the formation of Fe/CO/4N2. Mössbauer parameters of the products were obtained.

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Journal of Radionalytical and Nuclear Chemistry
Language English
Size A4
Year of
Foundation
1968
Volumes
per Year
1
Issues
per Year
12
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-5731 (Print)
ISSN 1588-2780 (Online)