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  • 1 Tokyo Metropolitan University Department of Chemistry, Faculty of Science Fukasawa, Setagaya-ku 158 Tokyo Japan
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Abstract  

Reaction products of [2]ferrocenophane with CF3COOH, CCl3COOH, CF3SO3H and SbCl5 were prepared. Mössbauer spectroscopic data and magnetic susceptibility measurements suggest the bond formation of Fe–H+ and Fe–Cl+, in which iron atoms are in a high-spin Fe/II/state.