Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 1: Issue 4
The thermal properties of some metal complexes of diethyldithiocarbamic acid new volatile metal chelates
Authors:
G. D'Ascenzo Thermochemistry Laboratory, Department of Chemistry University of Houston Houston Texas USA

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W. W. Wendlandt Thermochemistry Laboratory, Department of Chemistry University of Houston Houston Texas USA

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Pages:
423–434
Online Publication Date:
03 Aug 2005
Publication Date:
01 Dec 1969
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01983084
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The cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II), silver(I) and mercury(II) complexes of diethyldithiocarbamic acid were prepared and their thermal properties determined by TG, DTA, and high temperature reflectance spectroscopy. It was found that the copper(II), nickel(II), and zinc(II) chelates were completely volatile and thus represent a new class of volatile metal chelates. Vapor pressure measurements were made on four of the metal complexes; heats of vaporization ranged from 9.3±0.2 kcal/mole for Na[Co(DDC)3] to 24.2±0.6 kcal/mole for Zn(DDC)2.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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