Authors:
V. Logvinenko Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by V. Logvinenko in
Current site
Google Scholar
PubMed
Close
,
D. Dybtsev Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by D. Dybtsev in
Current site
Google Scholar
PubMed
Close
,
V. Fedin Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by V. Fedin in
Current site
Google Scholar
PubMed
Close
,
V. Drebushchak Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by V. Drebushchak in
Current site
Google Scholar
PubMed
Close
, and
M. Yutkin Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by M. Yutkin in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract  

The thermal decomposition of three inclusion compounds: [Zn2(camph)2dabco]·DMF·H2O, [Zn2(camph)2bipy]·3DMF·H2O and [Zn2(camph)2bpe]·5DMF·H2O was studied in the inert atmosphere. TG and DTG curves confirm multi-step decomposition process, the dehydration being the first step. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with ‘Model-free’ approach). Kinetic parameters of decomposition were calculated for the DMF multi-step removal, the processes are described by Avrami–Erofeev equations. The connection between the kinetic parameters and structural features of the host frameworks (ligand linker lengths and porous-free volumes) are discussed.

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Oct 2023 0 1 0
Nov 2023 1 0 0
Dec 2023 10 0 0
Jan 2024 3 0 0
Feb 2024 1 0 0
Mar 2024 2 0 0
Apr 2024 0 0 0