Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 100: Issue 1
The stability of inclusion compounds under heating
Part 2. Inclusion compounds of layered zinc camphorate, linked by linear N-donor ligands
Authors:
V. Logvinenko Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by V. Logvinenko in
Current site
Google Scholar
PubMed Close
,
D. Dybtsev Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by D. Dybtsev in
Current site
Google Scholar
PubMed Close
,
V. Fedin Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by V. Fedin in
Current site
Google Scholar
PubMed Close
,
V. Drebushchak Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by V. Drebushchak in
Current site
Google Scholar
PubMed Close
, and
M. Yutkin Siberian Branch of Russian Academy of Sciences Nikolaev Institute of Inorganic Chemistry Ac. Lavrentyev Ave. 3 630090 Novosibirsk-90 Russia

Search for other papers by M. Yutkin in
Current site
Google Scholar
PubMed Close
Pages:
183–189
Online Publication Date:
09 Oct 2009
Publication Date:
01 Apr 2010
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-009-0444-2
Restricted access

Abstract  

The thermal decomposition of three inclusion compounds: [Zn2(camph)2dabco]·DMF·H2O, [Zn2(camph)2bipy]·3DMF·H2O and [Zn2(camph)2bpe]·5DMF·H2O was studied in the inert atmosphere. TG and DTG curves confirm multi-step decomposition process, the dehydration being the first step. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with ‘Model-free’ approach). Kinetic parameters of decomposition were calculated for the DMF multi-step removal, the processes are described by Avrami–Erofeev equations. The connection between the kinetic parameters and structural features of the host frameworks (ligand linker lengths and porous-free volumes) are discussed.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2023 1 1 0
Jul 2023 0 0 0
Aug 2023 0 0 0
Sep 2023 2 0 0
Oct 2023 0 1 0
Nov 2023 1 0 0
Dec 2023 1 0 0