View More View Less
  • 1 Yokohama National University Graduate School of Environment and Information Sciences 79-7 Tokiwadai, Hodogaya-ku Yokohama Kanagawa 240-8501 Japan
Restricted access

Abstract  

In order to obtain a better understanding of thermal substituent effects in 1,2,4-triazole-3-one (TO), the thermal behavior of 1,2,4-triazole, TO, as well as urazole and the decomposition mechanism of TO were investigated. Thermal substituent effects were considered using thermogravimetry/differential thermal analysis, sealed cell differential scanning calorimetry, and molecular orbital calculations. The onset temperature of 1,2,4-triazole was higher than that of TO and urazole. Analyses of evolved decomposition gases were carried out using thermogravimetry–infrared spectroscopy and thermogravimetry–mass spectrometry. The gases evolved from TO were determined as HNCO, HCN, N2, NH3, CO2, and N2O.

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Nov 2020 0 0 0
Dec 2020 0 0 0
Jan 2021 2 1 1
Feb 2021 0 0 0
Mar 2021 0 0 0
Apr 2021 0 0 0
May 2021 0 0 0