Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 100: Issue 2
Comparisons of nth-order kinetic algorithms and kinetic model simulation on HMX by DSC tests
Authors:
Chun-Ping Lin National Yunlin University of Science and Technology (NYUST) Graduate School of Engineering Science and Technology 123, University Rd., Sec. 3 Douliou, Yunlin 64002 Taiwan, ROC

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Yi-Ming Chang National Yunlin University of Science and Technology (NYUST) Graduate School of Engineering Science and Technology 123, University Rd., Sec. 3 Douliou, Yunlin 64002 Taiwan, ROC

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Jo-Ming Tseng Central Taiwan University of Science and Technology Institute of Safety and Disaster Prevention Technology 666, Buzih Rd., Beitun District Taichung 40601 Taiwan, ROC

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Chi-Min Shu

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Pages:
607–614
Online Publication Date:
10 Dec 2009
Publication Date:
01 May 2010
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-009-0592-4
Keywords:
Differential scanning calorimetry (DSC); Energetic material; Kinetic algorithms; Kinetic; Model simulation; Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)
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Abstract  

Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) is a typical highly energetic material that has been widely used in national defense industries since the 1940s. The aim of this study was to establish a reaction kinetic model on thermal decomposition properties via differential scanning calorimetry (DSC) by well-known kinetic equations and kinetic model simulation. Furthermore, the aim also was to compare kinetic algorithms for thermal decomposition energy parameters under various conditions. Experimental results highly depended on the reliability of the kinetic concept applied, which is essentially defined by the proper choice of a mathematical model of a reaction. In addition, the correctness of the methods is used for kinetics evaluation.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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