Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 100: Issue 3
Low-temperature thermodynamics of Ln(Me2dtc)3(C12H8N2) (Me2dtc = dimethyldithiocarbamate, Ln = La, Pr, Nd, Sm)
Authors:
Jian Wu Northwest University Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science 710069 Xi’an Shaanxi People’s Republic of China

Search for other papers by Jian Wu in
Current site
Google Scholar
PubMed Close
,
San-Ping Chen Northwest University Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science 710069 Xi’an Shaanxi People’s Republic of China

Search for other papers by San-Ping Chen in
Current site
Google Scholar
PubMed Close
,
You-Ying Di Liaocheng Universtiy School of Chemistry and Chemical Engineering 252059 Liaocheng People’s Republic of China

Search for other papers by You-Ying Di in
Current site
Google Scholar
PubMed Close
, and
Sheng-Li Gao Northwest University Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science 710069 Xi’an Shaanxi People’s Republic of China

Search for other papers by Sheng-Li Gao in
Current site
Google Scholar
PubMed Close
Pages:
1091–1098
Online Publication Date:
28 Aug 2009
Publication Date:
01 Jun 2010
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-009-0390-z
Keywords:
Ln(Me2dtc)3(C12H8N2); Adiabatic calorimetry; Heat capacity
Restricted access

Abstract  

The heat capacities of Ln(Me2dtc)3(C12H8N2) (Ln = La, Pr, Nd, Sm, Me2dtc = dimethyldithiocarbamate) have been measured by the adiabatic method within the temperature range 78–404 K. The temperature dependencies of the heat capacities, Cp,m[La(Me2dtc)3(C12H8N2)] = 542.097 + 229.576 X − 27.169 X2 + 14.596 X3 − 7.135 X4 (J K−1 mol−1), Cp,m[Pr(Me2dtc)3(C12H8N2)] = 500.252 + 314.114 X − 17.596 X2 − 0.131 X3 + 16.627 X4 (J K−1 mol−1), Cp,m[Nd(Me2dtc)3(C12H8N2)] = 543.586 + 213.876 X − 68.040 X2 + 1.173 X3 + 2.563 X4 (J K−1 mol−1) and Cp,m[Sm(Me2dtc)3(C12H8N2)] = 528.650 + 216.408 X − 16.492 X2 + 12.076 X3 + 4.912 X4 (J K−1 mol−1), were derived by the least-squares method from the experimental data. The heat capacities of Ce(Me2dtc)3(C12H8N2) and Pm(Me2dtc)3(C12H8N2) at 298.15 K were evaluated to be 617.99 and 610.09 J K−1 mol−1, respectively. Furthermore, the thermodynamic functions (entropy, enthalpy and Gibbs free energy) have been calculated using the obtained experimental heat capacity data.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2024 0 0 0
Jul 2024 0 0 0
Aug 2024 7 0 0
Sep 2024 10 0 0
Oct 2024 58 0 0
Nov 2024 10 0 0
Dec 2024 0 0 0