Authors:
M. Pajtášová University of Trenčín Department of Chemical Technologies and Environment, Faculty of Industrial Technologies 020 01 Púchov Slovakia

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D. Ondrušová University of Trenčín Department of Chemical Technologies and Environment, Faculty of Industrial Technologies 020 01 Púchov Slovakia

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E. Jóna University of Trenčín Department of Chemical Technologies and Environment, Faculty of Industrial Technologies 020 01 Púchov Slovakia

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S. Mojumdar University of New Brunswick Department of Engineering Saint John NB E2L 4L5 Canada

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S. L’alíková University of Trenčín Department of Chemical Technologies and Environment, Faculty of Industrial Technologies 020 01 Púchov Slovakia

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T. Bazyláková University of Trenčín Department of Chemical Technologies and Environment, Faculty of Industrial Technologies 020 01 Púchov Slovakia

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M. Gregor Comenius University Bratislava Geological Institute, Faculty of Natural Sciences Mlynská Dolina 842 15 Bratislava Slovakia

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Abstract  

The carboxylato–Cu(II) complexes of type [Cu2(RCOO)4] and their benzothiazole adducts [Cu2(RCOO)4bt2] (bt = benzothiazole, R = CH3(CH2)n−2, n = 12, 14, 16, 18) form the main objectives of this study. The studied carboxylato–Cu(II) complexes are formed from dimeric units to polymeric chains (chromofor CuO5). The structural changes are due to coordination of ligand (benzothiazole). The polymeric chains of carboxylato–Cu(II) complexes degraded to discrete centrosymetric tetracarboxylate-bridged dimmers (chromofor CuO4N). These prepared compounds [Cu2(RCOO)4] and [Cu2(RCOO)4L2] were submitted to measurements relating to spectral (IR, UV–Vis) and thermal properties (TG, DTA, DSC).

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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