Authors:
E. Okeke University of Guelph Department of Chemistry 50 Stone Rd. E Guelph ON N1G 2W1 Canada

Search for other papers by E. Okeke in
Current site
Google Scholar
PubMed
Close
and
D. Soldatov University of Guelph Department of Chemistry 50 Stone Rd. E Guelph ON N1G 2W1 Canada

Search for other papers by D. Soldatov in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract  

Three isomorphous series of new compounds are reported: complexes [M(DBM)2Q2] and [M(DBM)2Iq2] (M = M(II) = Co, Ni, Zn, Cd; DBM is C6H5COCHCOC6H5) and inclusion compounds [M(DBM)2Q2]*Q (M = Co, Zn, Cd). All the compounds comprise a trans configured octahedral complex molecule. Inclusion compounds of modified Zn and Cd DBM complexes are reported for the first time and their inclusion ability is attributed to the trans isomeric state induced by the bulky Q or Iq ligand. The TG measurements indicate the following order of thermal stability of the complexes defined by the strength of the metal–ligand bonds: Ni > Co > Cd > Zn. The inclusion compounds do not follow this trend.

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Oct 2023 0 1 0
Nov 2023 4 3 0
Dec 2023 13 1 0
Jan 2024 7 0 0
Feb 2024 4 0 0
Mar 2024 2 0 0
Apr 2024 6 0 0