Dependence of kinetic parameters (activation energy and pre-exponential factor) and procedural factors (sample mass and heating
rate) independent of the reversibility and the type of reactions in non-isothermal thermogravimetry have been established.
Tris(ethylenediamine)nickel(II) oxalate dihydrate has been selected as a model complex and experiments were carried out at
different heating rates and sample masses to study the dependence quantitatively. The kinetic parameters calculated using
mechanistic and non-mechanistic equations show a systematic decrease with increase in either sample mass or heating rate for
the dehydration and deamination reactions. For the decomposition reaction, the kinetic parameters are not influenced by the
procedural factors. Mathematical correlations of high reliability are established between kinetic parameters and heating rate/sample
mass using both mechanistic and non-mechanistic equations for dehydration and deamination reactions. The quantification follows
an exponential decay of second order relation with respect to heating rate and a sigmoidal relation with regard to sample
mass for both the dehydration and deamination reactions. No quantitative correlation is possible for the final decomposition
stage. Thus, it is found that independent of the type of reaction (deamination or dehydration) the kinetic parameters have
a particular dependence on the procedural variables. The equations for exponential decay and sigmoidal dependence can be represented
as
respectively, where y represents kinetic parameters (E or A) and x represents the procedural variables (φ or m). Mechanism of the dehydration reaction is found to be random nucleation with the formation of one nucleus on each particle
and the deamination is a phase boundary reaction. It is observed that the mechanism of these reversible reactions is not affected
by the variation in sample mass and heating rate.