Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 101: Issue 3
Thermal properties of PA 6 and PA 6 modified with copolyamides and layered silicates
Authors:
J. Ryba Department of Fibres and Textile Chemistry, Faculty of Chemical and Food Technology, Institute of Polymer Materials, Slovak University of Technology in Bratislava, Bratislava, Radlinského 9, 812 37 Bratislava, Slovak Republic

Search for other papers by J. Ryba in
Current site
Google Scholar
PubMed Close
,
A. Ujhelyiová Department of Fibres and Textile Chemistry, Faculty of Chemical and Food Technology, Institute of Polymer Materials, Slovak University of Technology in Bratislava, Bratislava, Radlinského 9, 812 37 Bratislava, Slovak Republic

Search for other papers by A. Ujhelyiová in
Current site
Google Scholar
PubMed Close
,
M. Krištofič Department of Fibres and Textile Chemistry, Faculty of Chemical and Food Technology, Institute of Polymer Materials, Slovak University of Technology in Bratislava, Bratislava, Radlinského 9, 812 37 Bratislava, Slovak Republic

Search for other papers by M. Krištofič in
Current site
Google Scholar
PubMed Close
, and
I. Vassová Department of Fibres and Textile Chemistry, Faculty of Chemical and Food Technology, Institute of Polymer Materials, Slovak University of Technology in Bratislava, Bratislava, Radlinského 9, 812 37 Bratislava, Slovak Republic

Search for other papers by I. Vassová in
Current site
Google Scholar
PubMed Close
Pages:
1027–1037
Online Publication Date:
10 Mar 2010
Publication Date:
01 Sep 2010
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-010-0715-y
Keywords:
DSC; Copolyamides; Nanoadditives
Restricted access

Abstract  

This article focuses on the thermal properties of PA 6 and additives, i.e. ternary copolyamides, concentrates consisting of binary or ternary copolyamides + nanoadditive montmorillonite Bentonite 11958 or Cloisite 15A and PA 6 fibres modified with Bentonite, copolyamide and concentrate. The copolyamides are prepared from ε-caprolactam as a major comonomer and nylon salts AN2 from adipic acid + 1-(2-aminoethyl)piperazine and ADETA from adipic acid + diethylenetriamine. All copolyamides and concentrates exhibit lower melting temperatures Tm and lower melting enthalpies ΔHm compared to neat PA 6. PA 6 fibres modified with 0.25–2.5 wt% MMT exhibit higher melting enthalpies in comparison with unmodified PA 6 fibres. PA 6 fibres modified with 10 wt% of ternary copolyamide containing 21.4 wt% of comonomers AN2 and ADETA have higher melting enthalpy as well. PA 6 fibres modified with 10 and 20 wt% of concentrate containing the same ternary copolyamide + 5 wt% of MMT have higher melting enthalpies and higher tensile strength in comparison with these characteristics of unmodified PA 6 fibres.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2024 2 0 0
Jul 2024 24 0 0
Aug 2024 10 0 0
Sep 2024 6 0 0
Oct 2024 17 0 0
Nov 2024 5 0 0
Dec 2024 0 0 0