Author:
Małgorzata Jóźwiak Department of Physical Chemistry, University of Łódź, Pomorska 165, 90-236 Łódź, Poland

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Abstract  

The enthalpies of solution of cyclic ethers: 1,4-dioxane, 12-crown-4 (12C4), and 18-crown-6 (18C6) in water–acetone mixtures have been measured within the whole mole fraction range at 298.15 K. Based on the obtained data, the effect of base–acid properties of water–acetone mixtures on the solution enthalpy of cyclic ethers in this mixed solvent has been analyzed. The strong dependence of the enthalpy of solution (solvation) of cyclic ethers on basic properties of mixed solvent has been observed. The effects of carbonyl atom replacement in acetone (ACN) molecule by sulfur atom (DMSO molecule) and base–acid properties of mixed solvent on the solvation process of cyclic ethers have been analyzed.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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