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  • 1 Faculty of Chemistry, Institute of Polymers and Dye Technology, Technical University of Lodz, Lodz, Poland
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Abstract

The results of thermal analysis of speciality elastomers CSM with different chlorine and sulphur contents is presented in the article. The thermal curves obtained under the atmosphere of inert gas have been interpreted from the point of view of phase transitions and chemical reactions of the examined polymers during their heating. It has been stated that from among the investigated chlorosulphonated polyethylenes, only CSM24, which has the lowest chlorine content, contains a crystalline phase, clearly influences on its Tg temperature. Results of the thermal analysis obtained under inert gas atmosphere have been compared with results obtained under termooxidative atmosphere. Irrespective of the research atmosphere, the thermal decomposition of investigated CSM takes place in three stages. The maximum rate of thermal destruction of modified by heating elastomers, dm/dt, decreases with the increase in chlorine content in the sample having been heated.

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  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
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  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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