Authors:
Chun-Hong Jiang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, 116023, Dalian, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Li-Fang Song Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, 116023, Dalian, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Jian Zhang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, 116023, Dalian, People's Republic of China

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Li-Xian Sun Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, 116023, Dalian, People's Republic of China

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Fen Xu Fac. Chem. and Chem. Engn., Liaoning Normal University, Dalian 116029, People's Republic of China

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Fen Li Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, 116023, Dalian, People's Republic of China

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Qing-Zhu Jiao Fac. Chem. and Chem. Engn., Liaoning Normal University, Dalian 116029, People's Republic of China

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Zhen-Gang Sun Fac. Chem. and Chem. Engn., Liaoning Normal University, Dalian 116029, People's Republic of China

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Yong-Heng Xing Fac. Chem. and Chem. Engn., Liaoning Normal University, Dalian 116029, People's Republic of China

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Yong Du State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, People's Republic of China

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Ju-Lan Zeng School of Chemistry and Environmental Engineering, Changsha University of Science and Technology, Changsha 410076, People's Republic of China

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Zhong Cao School of Chemistry and Environmental Engineering, Changsha University of Science and Technology, Changsha 410076, People's Republic of China

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Abstract

A novel metal organic framework [Co (BTC)1/3 (DMF) (HCOO)]n (CoMOF, BTC = 1,3,5-benzene tricarboxylate, DMF = N,N-dimethylformamide) has been synthesized solvothermally and characterized by single crystal X-ray diffraction, X-ray powder diffraction, and FT-IR spectra. The molar heat capacity of the compound was measured by modulated differential scanning calorimetry (MDSC) over the temperature range from 198 to 418 K for the first time. The thermodynamic parameters such as entropy and enthalpy versus 298.15 K based on the above molar heat capacity were calculated. Moreover, a four-step sequential thermal decomposition mechanism for the CoMOF was investigated through the thermogravimetry and mass spectrometer analysis (TG-DTG-MS) from 300 to 800 K. The apparent activation energy of the first decomposition step of the compound was calculated by the Kissinger method using experimental data of TG analysis.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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